Metal-mediated reactions between dialkylcyanamides and acetamidoxime generate unusual (nitrosoguanidinate)nickel(ii) complexes-Reference-Cited by-同舟云学术

Metal-mediated reactions between dialkylcyanamides and acetamidoxime generate unusual (nitrosoguanidinate)nickel(ii) complexes

Published:2017 Issue:30 Volume:46 Page:10090-10101
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bikbaeva Zarina M.¹²³,Novikov Alexander S.¹²³^ORCID,Suslonov Vitalii V.¹²³^ORCID,Bokach Nadezhda A.¹²³^ORCID,Kukushkin Vadim Yu.¹²³^ORCID

Affiliation:

1. Saint Petersburg State University

2. 199034 Saint Petersburg

3. Russian Federation

Abstract

Nitrosoguanidinate Ni^II complexes were generated via a hitherto unreported reaction between nickel(ii) salts, N,N-disubstituted cyanamides NCNR₂, and the amidoxime MeC(NOH)NH₂ in MeOH.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01960B

Reference83 articles.

1. Coordination chemistry of dialkylcyanamides: Binding properties, synthesis of metal complexes, and ligand reactivity

2. Novel Tailoring Reaction for Two Adjacent Coordinated Nitriles Giving Platinum 1,3,5-Triazapentadiene Complexes

3. A Novel Reactivity Mode for Metal-Activated Dialkylcyanamide Species: Addition of N,N′-Diphenylguanidine to a cis-(R2NCN)2PtII Center Giving an Eight-Membered Chelated Platinaguanidine

4. Bifunctional activation of cyanoguanidine. Synthesis and molecular structure of the azametallacycle cis-[(PPh3)2Pt{NHC(OMe)=NC(NH2)=NH}][BPh4]

5. Hydrolytic Metal-Mediated Coupling of Dialkylcyanamides at a Pt(IV) Center Giving a New Family of Diimino Ligands

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