Reversible transformation of sub-nanometer Ga-based clusters to isolated <sup>[4]</sup>Ga<sub>(4Si)</sub> sites creates active centers for propane dehydrogenation-Reference-Cited by-同舟云学术

Reversible transformation of sub-nanometer Ga-based clusters to isolated ^[4]Ga_(4Si) sites creates active centers for propane dehydrogenation

Published:2024 Issue:2 Volume:14 Page:379-390
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Chen Zixuan¹^ORCID,Serykh Alexander I.²^ORCID,Kierzkowska Agnieszka¹^ORCID,Gajan David³,Docherty Scott R.⁴,Yakimov Alexander V.⁴,Abdala Paula M.¹^ORCID,Copéret Christophe⁴^ORCID,Florian Pierre⁵^ORCID,Fedorov Alexey¹^ORCID,Müller Christoph R.¹^ORCID

Affiliation:

1. Department of Mechanical and Process Engineering, ETH Zürich, Switzerland

2. Zelinsky Institute of Organic Chemistry, RAS, Moscow, Russia

3. Centre de RMN à hauts champs de Lyon, UMR 5082 (CNRS, ENS Lyon, Université Lyon 1), Université de Lyon, Villeurbanne F-69100, France

4. Department of Chemistry and Applied Biosciences, ETH Zürich, Switzerland

5. CNRS, CEMHTI UPR3079, Université d'Orléans, France

Abstract

This work describes how a propane dehydrogenation catalyst with isolated [4]Ga(4Si) sites can be prepared from silica-supported sub-nm gallia clusters containing [4]Ga(Ga) and [6]Ga(Ga) sites.

Funder

Eidgenössische Technische Hochschule Zürich

Horizon 2020 Framework Programme

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CY/D3CY01446K

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