Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation
Author:
Affiliation:
1. Department of Chemistry
2. University of California-Irvine
3. California 92697
4. USA
Abstract
A Rh-catalyzed desymmetrization of α,α-bis(allyl)aldehydes occurs by enantioselective isomerization followed by olefin-directed hydroacylation.
Funder
National Institutes of Health
Eli Lilly and Company
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01553G
Reference54 articles.
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4. Stereoselective Cyclopropanation Reactions
5. Enantioselective construction of remote quaternary stereocentres
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