Dimensional reduction upon calcium incorporation in Cs0.3(Ca0.3Ln0.7)PS4 and Cs0.5(Ca0.5Ln0.5)PS4

Author:

Klepov Vladislav V.1234ORCID,Kocevski Vancho56748ORCID,Besmann Theodore M.8234,zur Loye Hans-Conrad1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of South Carolina

3. Columbia

4. USA

5. MST-8

6. Los Alamos National Laboratory

7. Los Alamos

8. Department of Mechanical Engineering

Abstract

A series of Ca-containing lanthanide thiophosphates has been obtained and their structural evolution from 3D for LnPS4 and Cs0.3(Ln0.7Ca0.3)PS4 to 2D in Cs0.5(Ln0.5Ca0.5)PS4 was shown as a function of Ca content.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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