Aromatic character of [Au13]5+ and [MAu12]4+/6+ (M = Pd, Pt) cores in ligand protected gold nanoclusters – interplay between spherical and planar σ-aromatics-Reference-Cited by-同舟云学术

Aromatic character of [Au13]5+ and [MAu12]4+/6+ (M = Pd, Pt) cores in ligand protected gold nanoclusters – interplay between spherical and planar σ-aromatics

Published:2019 Issue:45 Volume:21 Page:25215-25219
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Fedik Nikita¹²³⁴,Boldyrev Alexander I.¹²³⁴^ORCID,Muñoz-Castro Alvaro⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Utah State University

3. Logan

4. USA

5. Grupo de Química Inorgánica y Materiales Moleculares

6. Facultad de Ingenieria

7. Universidad Autonoma de Chile

8. Santiago

9. Chile

Abstract

Ligand-protected superatoms are able to behave as both spherical and planar aromatic species, providing a strong link between spherical and planar σ-aromatics, which can be controlled selectively by tuning their redox charge states.

Funder

National Science Foundation

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP04477A

Reference75 articles.

1. Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system

2. Size-Focusing Synthesis, Optical and Electrochemical Properties of Monodisperse Au38(SC2H4Ph)24 Nanoclusters