Supramolecular assembly by time-programmed acid autocatalysis

Author:

Panzarasa Guido12345ORCID,Sai Tianqi12345,Torzynski Alexandre L.12345,Smith-Mannschott Katrina12345,Dufresne Eric R.12345

Affiliation:

1. Laboratory of Soft and Living Materials

2. Department of Materials

3. ETH Zürich

4. 8093 Zürich

5. Switzerland

Abstract

Coupling an acid-autocatalyzed clock reaction with the hydrolysis of a cyclic ester enables the time-domain programming of supramolecular pH-driven self-assembly.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Process Chemistry and Technology,Energy Engineering and Power Technology,Biomedical Engineering,Chemical Engineering (miscellaneous),Chemistry (miscellaneous)

Reference41 articles.

1. I. R. Epstein , J. A.Pojman and Q.Tran-Cong-Miyata , in Nonlinear Dynamics with Polymers: Fundamentals, Methods and Applications , ed. J. A. Pojman and Q. Tran-Cong-Miyata , Wiley-VCH Verlag GmbH & Co. , 2010 , pp. 5–19

2. Mechanisms of Autocatalysis

3. The Road to Non-Enzymatic Molecular Networks

4. What is and what isn’t a clock reaction?

5. Ester hydrolysis: Conditions for acid autocatalysis and a kinetic switch

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