Carbonate phosphonium salts as catalysts for the transesterification of dialkyl carbonates with diols. The competition between cyclic carbonates and linear dicarbonate products-Reference-Cited by-同舟云学术

Carbonate phosphonium salts as catalysts for the transesterification of dialkyl carbonates with diols. The competition between cyclic carbonates and linear dicarbonate products

Published:2014 Issue:24 Volume:12 Page:4143-4155
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Selva Maurizio¹²³⁴,Caretto Alessio¹²³⁴,Noè Marco¹²³⁴,Perosa Alvise¹²³⁴

Affiliation:

1. Department of Molecular Sciences and Nanosystems

2. Centre for Sustainable Technologies

3. Università Ca’ Foscari Venezia

4. 2137-30123 - Venezia, Italy

Abstract

Methylcarbonate and bicarbonate methyltrioctylphosphonium salts were excellent catalysts for the transesterification of dialkyl carbonates with diols: cyclic or linear carbonates are obtained.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00655K

Reference44 articles.

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