Modular design of a zwitterionic organocatalyst for bulk ring-opening polymerization of cyclic esters-Reference-Cited by-同舟云学术

Modular design of a zwitterionic organocatalyst for bulk ring-opening polymerization of cyclic esters

Published:2024 Issue:35 Volume:15 Page:3572-3587
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Guo Fengzhen¹,Guo Peng²^ORCID,Li Zhenjiang¹^ORCID,Yin Yaling¹,Yu Hui¹,Cao Shaoju¹,Li Chunyu¹,Zou Xin¹,Lyu Mingfu²,Guo Kai¹^ORCID

Affiliation:

1. State Key Laboratory Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 Puzhu Road South, Nanjing 211816, China

2. Beijing Research Institute of Chemical Industry, SINOPEC, Beijing 100013, P. R. China

Abstract

Zwitterionic organocatalysis in the ring-opening polymerizations of cyclic esters via bifunctional activation of the monomer by Lewis acidic cation and the chain-end by Lewis basic anion of the modular designed phoshonium carboxybetaines.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Jiangsu National Synergistic Innovation Center for Advanced Materials

SINOPEC Petroleum Exploration and Production Research Institute

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00678J

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4. A roadmap towards green packaging: the current status and future outlook for polyesters in the packaging industry

5. Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers