The influence of loops on the binding of the [Ru(phen)2dppz]2+ light-switch compound to i-motif DNA structures revealed by time-resolved spectroscopy

Author:

Baptista Frederico R.1234,Devereux Stephen J.1234,Gurung Sarah P.56789,Hall James P.567810ORCID,Sazanovich Igor V.111213148,Towrie Michael111213148,Cardin Christine J.5678ORCID,Brazier John A.10678,Kelly John M.115164ORCID,Quinn Susan J.1234ORCID

Affiliation:

1. School of Chemistry

2. University College Dublin

3. Dublin 4

4. Ireland

5. Department of Chemistry

6. University of Reading

7. Reading

8. UK

9. Diamond Light Source

10. School of Pharmacy

11. Central Laser Facility

12. Rutherford Appleton Laboratory

13. STFC

14. Harwell Campus

15. Trinity College Dublin

16. Dublin 2

Abstract

Ultrafast time resolved infrared (TRIR) is used to report on the binding site of the “light-switch” complex [Ru(phen)2(dppz)]2+ to i-motif structures in solution.

Funder

Irish Research Council

Biotechnology and Biological Sciences Research Council

Science and Technology Facilities Council

University College Dublin

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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