Non-traditional thermal behavior of Co(ii) coordination networks showing slow magnetic relaxation

Author:

Świtlicka Anna1ORCID,Machura Barbara1ORCID,Bieńko Alina2ORCID,Kozieł Sandra2ORCID,Bieńko Dariusz C.3ORCID,Rajnák Cyril4ORCID,Boča Roman4ORCID,Ozarowski Andrew5ORCID,Ozerov Mykhaylo5ORCID

Affiliation:

1. Department of Crystallography, Institute of Chemistry, University of Silesia, 9 Szkolna St., 40-006 Katowice, Poland

2. Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie, 50-383 Wroclaw, Poland

3. Faculty of Chemistry, Wroclaw University of Technology, Wybrzeze Wyspiańskiego 27, 50-370 Wroclaw, Poland

4. Department of Chemistry, Faculty of Natural Sciences, University of SS Cyril and Methodius, 917 01 Trnava, Slovakia

5. National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, Florida 32310, USA

Abstract

Three new Co(ii) coordination polymers show the DC magnetic data consistent with the S = 3/2 spin system with large zero-field splitting D > 0, which was confirmed by HF EPR and FIRMS measurements.

Funder

National Science Foundation

Ministerstvo školstva, vedy, výskumu a športu Slovenskej republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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