One-pot synthesis of amides via the oxidative amidation of aldehydes and amines catalyzed by a copper-MOF-Reference-Cited by-同舟云学术

One-pot synthesis of amides via the oxidative amidation of aldehydes and amines catalyzed by a copper-MOF

Published:2019 Issue:39 Volume:9 Page:22749-22754
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Jamalifard Samira¹²³⁴⁵,Mokhtari Javad¹²³⁴⁵^ORCID,Mirjafary Zohreh¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Science and Research Branch

3. Islamic Azad University

4. Tehran

5. Iran

Abstract

A method for oxidative amidation of aldehydes with primary amines was developed to synthesise a variety of amides using Cu₂(BDC)₂DABCO (Cu-MOF) as a recyclable heterogeneous catalyst, and N-chlorosuccinimide and aqueous tert-butyl hydroperoxide as oxidants in acetonitrile.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA04216D

Reference68 articles.

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2. Amide bond formation: beyond the myth of coupling reagents

3. R. C.Larock , Comprehensive Organic Transformations , VCH , New York , 1999

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