Rhodium-catalyzed ortho-heteroarylation of phenols: directing group-enabled switching of the electronic bias for heteroaromatic coupling partner-Reference-Cited by-同舟云学术

Rhodium-catalyzed ortho-heteroarylation of phenols: directing group-enabled switching of the electronic bias for heteroaromatic coupling partner

Published:2018 Issue:33 Volume:9 Page:6878-6882
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Yimin¹²³⁴⁵,Li Wei¹²³⁴⁵,Jiang Linfeng¹²³⁴⁵,Zhang Luoqiang¹²³⁴⁵,Lan Jingbo¹²³⁴⁵^ORCID,You Jingsong¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry and Technology of Ministry of Education

2. College of Chemistry

3. Sichuan University

4. Chengdu 610064

5. PR China

Abstract

A highly efficient ortho-heteroarylation of phenols with diverse electron-rich heteroarenes has been developed to forge heteroaryl-2-hydroxyphenyl structural motifs. The removal of the directing group and subsequent intramolecular cyclization make this protocol applicable in the rapid construction of π-conjugated heteroacenes.

Funder

National Natural Science Foundation of China

Sichuan University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02529K

Reference59 articles.

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