Positively and negatively charged NHN hydrogen bonds in one molecule: synergistic strengthening effect, superbasicity and acetonitrile capture-Reference-Cited by-同舟云学术

Positively and negatively charged NHN hydrogen bonds in one molecule: synergistic strengthening effect, superbasicity and acetonitrile capture

Published:2019 Issue:20 Volume:43 Page:7557-7561
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Vlasenko Marina P.¹²³,Ozeryanskii Valery A.¹²³^ORCID,Pozharskii Alexander F.¹²³^ORCID,Khoroshilova Olesya V.⁴⁵³

Affiliation:

1. Department of Organic Chemistry, Southern Federal University

2. 344090 Rostov-on-Don

3. Russian Federation

4. Institute of Chemistry, St. Petersburg State University

5. 198504 St. Petersburg

Abstract

The first full nitrogen zwitterions were synthesized. Both [NHN]⁻ and [NHN]⁺ bridges strongly influence each other, resulting in superbasicity and receptor properties.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ00965E

Reference33 articles.

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3. Heterocyclic superbases: retrospective and current trends

4. Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts , ed. T. Ishikawa , J. Wiley & Sons , Chichester , 2009

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