Experimental and theoretical studies on the extraction behavior of Cf(<scp>iii</scp>) by NTAamide(C8) ligand and the separation of Cf(<scp>iii</scp>)/Cm(<scp>iii</scp>)-Reference-Cited by-同舟云学术

Experimental and theoretical studies on the extraction behavior of Cf(iii) by NTAamide(C8) ligand and the separation of Cf(iii)/Cm(iii)

Published:2023 Issue:6 Volume:13 Page:3781-3791
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Yi-lin¹,Li Feng-feng¹,Xiao Zhe¹,Wang Cong-zhi²,Liu Yang²,Shi Wei-qun²^ORCID,He Hui¹^ORCID

Affiliation:

1. Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, P. R. China

2. Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

We performed basic chemical studies on Cf using NTAamide extractant. The results of experiments and DFT calculations show that NTAamide has a good coordination ability to Cf/Cm and is expected to be applied to Cf/Cm separation.

Funder

China Institute of Atomic Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D2RA07660H

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