<i>C</i><sub>1</sub>-Symmetric {cyclopentadienyl/indenyl}-metallocene catalysts: synthesis, structure, isospecific polymerization of propylene and stereocontrol mechanism-Reference-Cited by-同舟云学术

C₁-Symmetric {cyclopentadienyl/indenyl}-metallocene catalysts: synthesis, structure, isospecific polymerization of propylene and stereocontrol mechanism

Published:2023 Issue:25 Volume:52 Page:8620-8630
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Theodosopoulou Dimitra¹,De La Pena Miguel Alonso¹,Abou Derhamine Sary¹,Douair Iskander²,Roisnel Thierry³^ORCID,Cordier Marie³,Piola Lorenzo⁴,Fernandez Alvaro⁴,Welle Alexandre⁴,Maron Laurent²^ORCID,Carpentier Jean-François¹^ORCID,Kirillov Evgueni¹^ORCID

Affiliation:

1. Univ Rennes, CNRS, Institut des Sciences Chimiques de Rennes (ISCR), UMR 6226, F-35042 Rennes, France

2. Univ Toulouse, INSA, UPS and CNRS, LPCNO, UMR 5215, F-31077 Toulouse, France

3. Centre de diffraction X, Univ Rennes, CNRS, ISCR, UMR 6226, F-35700 Rennes, France

4. TotalEnergies, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium

Abstract

A series of new Me2Si-bridged cyclopentadiene/indene proligands {Me2Si(R2′,5′2-R3′,4′2-Cp)(R2,R4,R5,R6-Ind)H2} (1a–j) with various substitutions both on the indene and cyclopentadiene moieties was prepared.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01306E

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