Influence of the central diamagnetic cyanidometal on the distant magnetic interaction in cyanide-bridged Fe(iii)–M(ii)–Fe(iii) complexes
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou
5. China
Abstract
This work shows that for the investigated FeIII–NC–MII–CN–FeIII complexes the magnetic coupling strength between the distant FeIII ions increases with the diamagnetic cyanidometal bridge in the order of Fe < Ru < Os.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00383K
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