Unusual stoichiometry, band structure and band filling in conducting enantiopure radical cation salts of TM-BEDT-TTF showing helical packing of the donors-Reference-Cited by-同舟云学术

Unusual stoichiometry, band structure and band filling in conducting enantiopure radical cation salts of TM-BEDT-TTF showing helical packing of the donors

Published:2021 Issue:33 Volume:9 Page:10777-10786
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Pop Flavia¹,Mézière Cécile¹,Allain Magali¹,Auban-Senzier Pascale²,Tajima Naoya³,Hirobe Daichi⁴⁵⁶,Yamamoto Hiroshi M.⁴⁵,Canadell Enric⁷^ORCID,Avarvari Narcis¹^ORCID

Affiliation:

1. Univ. Angers, CNRS, MOLTECH-Anjou, SFR MATRIX, F-49000 Angers, France

2. Laboratoire de Physique des Solides, Université Paris-Saclay CNRS UMR 8502, Bât. 510, 91405 Orsay, France

3. Department of Physics, Toho University, Funabashi, Chiba 274-8510, Japan

4. Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan

5. SOKENDAI (Graduate University for Advanced Studies), Myodaiji, Okazaki 444-8585, Japan

6. PRESTO, Japan Science and Technology Agency (JST), Kawaguchi 332-0012, Japan

7. Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, E-08193 Bellaterra, Spain

Abstract

Enantiopure semiconducting crystalline radical cation salts of TM-BEDT-TTF with the Lindqvist type molybdenum based dianion, prepared by electrocrystallization, show unusual donor/anion ratio, charge distribution and helical packing of the donors.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Ministerio de Ciencia, Innovación y Universidades

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry