Revisiting cyclophanes: experimental characterization and theoretical elucidation of the chain length influence on their structure and reactivity-Reference-Cited by-同舟云学术

Revisiting cyclophanes: experimental characterization and theoretical elucidation of the chain length influence on their structure and reactivity

Published:2022 Issue:14 Volume:46 Page:6609-6621
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Castillo Francisco¹²^ORCID,Faúndez Rodrigo³,Tapia Jorge³⁴^ORCID,Verdugo Camilo¹,Preite Marcelo¹,Chávez Ivonne³,Manuel-Manriquez Juan³,Ortiz Pedro D.⁵^ORCID,Zarate Ximena⁵,Schott Eduardo³⁶^ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultad de Química, Pontificia Universidad Católica de Chile, Avenida Vicuña Mackenna 4860, Macul, 7820244, Santiago, Chile

2. Instituto de Ingeniería Biológica y Médica, IIMB, Pontificia Universidad Católica de Chile, Avenida Vicuña Mackenna 4860, Macul, 7820244, Santiago, Chile

3. Departamento de Química Inorgánica, Facultad de Química y Farmacia, Centro de Energía UC, Centro de Investigación en Nanotecnología y Materiales Avanzados CIEN-UC, Pontificia Universidad Católica de Chile, Avenida Vicuña Mackenna, 4860, Macul, 7820244, Santiago, Chile

4. Departamento de Ciencias Químicas y Biológicas, Universidad Bernardo O’Higgins, Facultad de Salud, General Gana, 1702, Santiago, Chile

5. Instituto de Ciencias Químicas Aplicadas, Facultad de Ingeniería, Universidad Autónoma de Chile, Av. Pedro de Valdivia 425, Providencia, 7500912, Chile

6. Millennium Nuclei on Catalytic Processes towards Sustainable Chemistry (CSC), Santiago, Chile

Abstract

[n]Paracyclophanes and dioxa[n]paracyclophanes were theoretically studied and synthesized, and it was found that n = 10 was the best candidate and showed improved yields.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Ministerio de Economía, Fomento y Turismo

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00151A

Reference39 articles.

1. Zur Kenntnis des Kohlenstoffringes XIX. Über 16-gliedrige m- und p-Benzo-polymethylenringe

2. Macrocyclic Esters1

3. Preparation and Structure of Di-p-Xylylene

4. Synthesis of a Benzene Ring with a Ten-Membered Para-Bridge

5. Macro Rings. I. Preparation and Spectra of the Paracyclophanes

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