Ruthenium nitrosyl complexes with the molecular framework [RuII(dmdptz)(bpy)(NO)]n+ (dmdptz: N,N-dimethyl-4,6-di(pyridin-2-yl)-1,3,5-triazin-2-amine and bpy: 2,2′-bipyridine). Electronic structure, reactivity aspects, photorelease, and scavenging of NO-Reference-Cited by-同舟云学术

Ruthenium nitrosyl complexes with the molecular framework [RuII(dmdptz)(bpy)(NO)]n+ (dmdptz: N,N-dimethyl-4,6-di(pyridin-2-yl)-1,3,5-triazin-2-amine and bpy: 2,2′-bipyridine). Electronic structure, reactivity aspects, photorelease, and scavenging of NO

Published:2020 Issue:43 Volume:44 Page:18732-18744
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Giri Bishnubasu¹²³⁴,Kumbhakar Sadananda¹²³⁴,Selvan K Kalai¹²³⁴,Muley Arabinda¹²³⁴,Maji Somnath¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Sangareddy 502285

4. India

Abstract

Two ruthenium nitrosyl complexes have been stabilized both in {Ru–NO}⁶ and {Ru–NO}⁷ configurations which show facile photocleavage of Ru–NO bond on exposure to visible light. The photo liberated NO is captured by reduced myoglobin.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ03923C

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