Spectroscopic characterization and photochemistry of the vinylsulfinyl radical-Reference-Cited by-同舟云学术

Spectroscopic characterization and photochemistry of the vinylsulfinyl radical

Published:2021 Issue:30 Volume:23 Page:16307-16315
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Zhuang¹²³⁴⁵,Wang Lina¹²³⁴⁵,Lu Bo¹²³⁴⁵,Eckhardt André K.⁶⁷⁸⁹^ORCID,Schreiner Peter R.⁶⁷⁸⁹^ORCID,Zeng Xiaoqing¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials

3. Fudan University

4. Shanghai

5. China

6. Institute of Organic Chemistry

7. Justus-Liebig University

8. 35392 Giessen

9. Germany

Abstract

The simplest α,β-unsaturated sulfinyl radical CH₂C(H)SO˙ has been generated and characterized with matrix-isolation IR and UV/Vis spectroscopy. In addition to the cis ⇋ trans conformational interconversion, its photochemistry and bonding properties have been disclosed.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02584H

Reference77 articles.

1. Relocalization in Floppy Free Radicals: The OCNO and OCCHO Isoelectronic Series

2. Relocalization in Floppy Free Radicals: Ab Initio Calculations of the C3H3O Isomers