Supramolecular encapsulation of hexaaquacobalt(ii) cations in a hydrogen-bonded framework for slow magnetic relaxation and high proton conduction

Author:

Shao Dong12ORCID,Zhou Yue1,Yang Xiaodong1ORCID,Yue Jing1,Ming Shujun1,Wei Xiao-Qin3ORCID,Tian Zhengfang1ORCID

Affiliation:

1. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, P. R. China

2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, P. R. China

3. Department of Material Science and Engineering, Shanxi Province Collaborative Innovation Center for Light Materials Modification and Application, Jinzhong University, Jinzhong, 030619, P. R. China

Abstract

A cobalt-based hydrogen-bonded organic framework (HOF) was reported to show field-induced single-ion magnet (SIM) behavior and high proton conductivity, representing the first example of a proton-conducting SIM-HOF.

Funder

Huanggang Normal University

State Key Laboratory of Coordination Chemistry

Shanxi University

Hubei Provincial Department of Education

Jinzhong University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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