Hemisynthesis of deuteriated adenosylhopane and conversion into bacteriohopanetetrol by a cell-free system from Methylobacterium organophilum-Reference-Cited by-同舟云学术

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Hemisynthesis of deuteriated adenosylhopane and conversion into bacteriohopanetetrol by a cell-free system from Methylobacterium organophilum

Published:2015 Issue:11 Volume:13 Page:3393-3405
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Liu Wenjun¹²³⁴,Bodlenner Anne¹⁵⁶⁴,Rohmer Michel¹²³⁴

Affiliation:

1. Université de Strasbourg/CNRS

2. Institut Le Bel

3. F 67070 Strasbourg

4. France

5. ECPM

6. F 67087 Strasbourg

Abstract

(²H₂)Adenosylhopane was synthesised via a reaction sequence including a cross metathesis followed by N₂²H₂ reduction of the resulting olefin.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02560A

Reference42 articles.

1. A novel hopanoid, 30-(5'-adenosyl)hopane, from the purple non-sulphur bacterium Rhodopseudomonas acidophila, with possible DNA interactions

2. The hopanoids of the purple non-sulfur bacteria Rhodopseudomonas palustris and Rhodopseudomonas acidophila and the absolute configuration of bacteriohopanetetrol

3. Novel bacterial triterpenoids of the hopane series from Nitrosomonas europaea and their significance for the formation of the C35 bacteriohopane skeleton

4. Novel methylated triterpenoids of the gammacerane series from the nitrogen-fixing bacterium Bradyrhizobium japonicum USDA 110

5. Oxidation of Fe(II) leads to increased C-2 methylation of pentacyclic triterpenoids in the anoxygenic phototrophic bacteriumRhodopseudomonas palustrisstrain TIE-1

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1. Biochemical and Mutational Analysis of Radical S-Adenosyl-L-Methionine Adenosylhopane Synthase HpnH from Zymomonas mobilis Reveals that the Conserved Residue Cysteine-106 Reduces a Radical Intermediate and Determines the Stereochemistry;Biochemistry;2021-09-10

2. Alkene Cross‐Metathesis Reactions;Organic Reactions;2021-06-15

3. Aminocyclitols;Comprehensive Natural Products III;2020

4. Characterization of Radical SAM Adenosylhopane Synthase, HpnH, which Catalyzes the 5 ′ ‐Deoxyadenosyl Radical Addition to Diploptene in the Biosynthesis of C 35 Bacteriohopanepolyols;Angewandte Chemie International Edition;2019-11-19

5. Characterization of Radical SAM Adenosylhopane Synthase, HpnH, which Catalyzes the 5 ′ ‐Deoxyadenosyl Radical Addition to Diploptene in the Biosynthesis of C 35 Bacteriohopanepolyols;Angewandte Chemie;2019-11-19

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