Single crystal growth and structure analysis of type-I (Na/Sr)–(Ga/Si) quaternary clathrates-Reference-Cited by-同舟云学术

Single crystal growth and structure analysis of type-I (Na/Sr)–(Ga/Si) quaternary clathrates

Published:2019 Issue:26 Volume:9 Page:14586-14591
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Urushiyama Hironao¹²³⁴⁵,Morito Haruhiko⁶²³⁴^ORCID,Yamane Hisanori¹²³⁴^ORCID

Affiliation:

1. Institute of Multidisciplinary Research for Advanced Materials

2. Tohoku University

3. Sendai 980-8577

4. Japan

5. Department of Metallurgy, Materials Science and Materials Processing

6. Institute for Materials Research

Abstract

Single crystals of (Na/Sr)–(Ga/Si) quaternary type-I clathrates, Na_8−ySr_yGa_xSi_46−x, were synthesized by evaporating Na from a mixture of Na–Sr–Ga–Si–Sn in a 6 : 0.5 : 1 : 2 : 1 molar ratio at 773 K for 12 h in an Ar atmosphere.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA01489F

Reference19 articles.

1. Clathrate Structure of Silicon Na 8 Si 46 and Na x Si 136 ( x < 11)

2. Sur les phases de type clathrate du silicium et des éléments apparentés (C, Ge, Sn) : Une approche historique

3. High-Pressure Synthesis of a New Silicon Clathrate Superconductor, Ba8Si46

4. Synthesis, Structure, Thermoelectric Properties, and Band Gaps of Alkali Metal Containing Type I Clathrates: A8Ga8Si38 (A = K, Rb, Cs) and K8Al8Si38

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