Control of Fe<sup>3+</sup> coordination by excess Cl<sup>−</sup> in alcohol solutions-Reference-Cited by-同舟云学术

Control of Fe³⁺ coordination by excess Cl⁻ in alcohol solutions

Published:2022 Issue:28 Volume:12 Page:17932-17936
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Nomura Yunika¹,Inoue Dai²,Moritomo Yutaka¹²³⁴^ORCID

Affiliation:

1. School of Science and Engineering, University of Tsukuba, Tsukuba 305-8571, Japan

2. Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan

3. Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan

4. Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, Tsukuba 305-8571, Japan

Abstract

Fe3+ coordination in alcohol solution can be controlled by the Cl− concentration ([Cl−]). The coordination state changes from FeL6 (L: solvent molecule) to FeCl4 type via FeClnL6−n with increases in [Cl−].

Funder

Murata Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA01522F

Reference33 articles.

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