Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol
Author:
Affiliation:
1. Instituto de Tecnología Química
2. Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas
3. E-46022 Valencia
4. Spain
Abstract
A chiral mesoporous hybrid material, containing inserted bis-silylated pyrrolidine building fragments in the framework, for enantioselective Michael addition with high stereocontrol.
Funder
H2020 European Research Council
Ministerio de Economía y Competitividad
Horizon 2020
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY01650J
Reference62 articles.
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3. Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
4. The Catalytic Asymmetric Aldol Reaction
5. K. Drauz and H.Waldmann , Enzyme Catalysis in Organic Synthesis , WCH , Weinheim , 1995
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