New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes-Reference-Cited by-同舟云学术

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New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes

Published:2016 Issue:107 Volume:6 Page:105969-105979
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Giannopoulos Dimosthenis P.¹²³⁴,Cunha-Silva Luís⁵⁶⁷⁸⁹,Ballesteros-Garrido Rafael¹⁰¹¹¹²¹³¹⁴,Ballesteros Rafael¹⁰¹¹¹²¹³¹⁴,Abarca Belén¹⁰¹¹¹²¹³¹⁴,Escuer Albert¹⁵¹⁶¹⁷¹⁸¹⁴,Stamatatos Theocharis C.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Brock University

3. L2S 3A1 St. Catharines

4. Canada

5. REQUIMTE-LAQV

6. Department of Chemistry and Biochemistry

7. Faculty of Sciences

8. University of Porto

9. 4169-007 Porto

10. Departamento de Química Orgánica

11. Faculdad de Farmacia

12. Universidad de Valencia

13. 46100 Burjassot

14. Spain

15. Departament de Quimica Inorganica i Organica

16. Seccio Inorgànica and Institut de Nanociencia i Nanotecnologia (IN2UB)

17. Universitat de Barcelona

18. 08028 Barcelona

Abstract

The ketone/gem-diol (L1H₂) and bis(gem-diol) (L2H₄) forms of the ligand 2,6-di-(2-pyridylcarbonyl)pyridine in Mn cluster chemistry have afforded the new complexes [MnII4MnIII2(N₃)₆Cl₄(L1)₂(DMF)₄] and [MnII4MnIII6O₂(N₃)₁₂(L1)₂(L2H)₂(DMF)₆].

Funder

Natural Sciences and Engineering Research Council of Canada

Ministerio de Economía y Competitividad

Brock University

Fundação para a Ciência e a Tecnologia

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22953K

Reference95 articles.

1. Giant Single-Molecule Magnets: A{Mn84} Torus and Its Supramolecular Nanotubes

2. A Ring of Rings and Other Multicomponent Assemblies of Cages

3. Linking Centered Manganese Triangles into Larger Clusters: A {Mn32} Truncated Cube

4. A [Mn32] Double-Decker Wheel

5. Magnetic “Molecular Oligomers” Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25 Na4 Fragment

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1. Gem‐diol Generation in Copper and Zinc N‐methyl‐2‐imidazolecarboxaldehyde Complexes: Solid‐state NMR, EPR and Single‐Crystal X‐ray Studies;European Journal of Inorganic Chemistry;2023-01-18

2. Shared Hydrogen Atom Location and Chemical Composition in Picolinic Acid and Pyridoxal Hydrochloride Derivatives Determined by X-ray Crystallography;The Journal of Organic Chemistry;2022-09-08

3. Paramagnetic solid-state NMR assignment and novel chemical conversion of the aldehyde group to dihydrogen ortho ester and hemiacetal moieties in copper(ii)- and cobalt(ii)-pyridinecarboxaldehyde complexes;RSC Advances;2021

4. gem ‐Diol‐Type Intermediate in the Activation of a Ketone on Sn‐β Zeolite as Studied by Solid‐State NMR Spectroscopy;Angewandte Chemie International Edition;2020-06-29

5. gem ‐Diol‐Type Intermediate in the Activation of a Ketone on Sn‐β Zeolite as Studied by Solid‐State NMR Spectroscopy;Angewandte Chemie;2020-06-29

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