Prolonging the exciton diffusion length by manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells to achieve over 19% efficiency

Author:

Wang Ke1,Zhao Fuwen1ORCID,Zhu Yufan1,He Yi1,Liu Zesheng2,Han Xiao3,Ai Qi1,Shen Xingxing4,Li Bao5,Zhang Jianqi6ORCID,Lin Yuze2ORCID,Wang Chunru2ORCID,He Dan1ORCID

Affiliation:

1. State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

2. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids and Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

3. College of Materials Science and Opto-Electronic Technology & Center of Materials Science and Optoelectronics Engineering & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

4. College of Chemical Engineering, Hebei Normal University of Science &Technology, Qinhuangdao 066004, P. R. China

5. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P.R. China

6. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China

Abstract

A solid additive, SA-5F, is employed to promote molecular stacking, which leads to higher crystallinity, boosting the exciton diffusion coefficient and then exciton diffusion length. Thus, D18/Y6+-based PPHJ OSCs afford an impressive PCE of 19.11%.

Funder

Natural Science Foundation of Hunan Province

National Natural Science Foundation of China

Science and Technology Program of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

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