Reaction of an N/Al FLP-based aluminum hydride toward alkynes: deprotonated alumination versus hydroalumination with regioselective cis-addition character-Reference-Cited by-同舟云学术

Reaction of an N/Al FLP-based aluminum hydride toward alkynes: deprotonated alumination versus hydroalumination with regioselective cis-addition character

Published:2019 Issue:25 Volume:48 Page:9152-9160
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Yilin¹²³⁴⁵,Jiang Wenjun¹²³⁴⁵,Li Bin¹²³⁴⁵,Fu Gang¹²³⁴⁵,Chen Shimin¹²³⁴⁵,Zhu Hongping¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces

2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen

Abstract

The reactions of an N/Al FLP-based aluminum hydride with a terminal alkyne yielded the deprotonated alumination compound, while that with an internal alkyne yielded a hydroalumination product.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00903E

Reference56 articles.

1. Applications of Diisobutylaluminium Hydride (DIBAH) and Triisobutylaluminium (TIBA) as Reducing Agents in Organic Synthesis

2. J. J. Eisch , in Comprehensive Organic Synthesis , ed. B. Frost and I. Fleming , Pergamon , Oxford , 1992 , vol. 8 , p. 733

3. G. Zweifel , in Aspects of Mechanism and Organometallic Chemistry , ed. J. H. Brewster , Plenum Press , New York , 1978 , p. 229

4. G. Zweifel , in Comprehensive Organic Chemistry , ed. D. H. R. Barton and W. D. Ollis , Pergamon , Oxford , 1979 , p. 1013

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Aluminum in Frustrated Lewis Pair Chemistry;Angewandte Chemie International Edition;2024-07-17

2. Aluminium in der Chemie der Frustrierten Lewis‐Paare;Angewandte Chemie;2024-07-17

3. Reactivity of Oxygen‐Bridged Geminal Al/P and Si/P Frustrated Lewis Pairs towards Heterocumulenes;Chemistry – A European Journal;2023-03-09

4. Four-membered C^N chelation in main-group organometallic chemistry;Dalton Transactions;2023

5. o ‐Phenylene‐ and o‐ benzyl‐linked P/N−Si/Sn Lewis pairs;Zeitschrift für anorganische und allgemeine Chemie;2022-12-22