Reaction of an N/Al FLP-based aluminum hydride toward alkynes: deprotonated alumination versus hydroalumination with regioselective cis-addition character
Author:
Affiliation:
1. State Key Laboratory of Physical Chemistry of Solid Surfaces
2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters
3. College of Chemistry and Chemical Engineering
4. Xiamen University
5. Xiamen
Abstract
The reactions of an N/Al FLP-based aluminum hydride with a terminal alkyne yielded the deprotonated alumination compound, while that with an internal alkyne yielded a hydroalumination product.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00903E
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