Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other?-Reference-Cited by-同舟云学术

Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other?

Published:2021 Issue:50 Volume:11 Page:31817-31826
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ali Amjad¹^ORCID,Nadeem Muhammad²^ORCID,Lu Jinwei¹,Moradian Jamile Mohammadi¹,Rasheed Tahir³^ORCID,Aziz Tariq³^ORCID,Maouche Chanez¹,Guo Yintian³,Awais Muhammad⁴,Zhiqiang Fan⁵^ORCID,Quo Li¹^ORCID

Affiliation:

1. Research School of Polymeric Materials Science & Engineering, Jiangsu University, Zhenjiang, 212013, PR China

2. Department of Environmental Engineering, Wuhang University of Technology, Wuhan, 430223, PR China

3. Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

4. Research Center of Fluid Machinery Engineering and Technology, Jiangsu University, Zhenjiang, 212013, PR China

5. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, PR China

Abstract

The kinetics and mechanism of ethylene and 5-ethylidene-2-norbornene copolymerization catalyzed by rac-Et(Ind)2ZrCl2 were investigated using 2-thiophenecarbonyl chloride.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA06243C

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3. Kinetics of short-duration ethylene-propylene copolymerization with MgCl2 -supported Ziegler-Natta catalyst: Differentiation of active centers on the external and internal surfaces of the catalyst particles