Synthesis of tailored hydrodipyrrins and their examination in directed routes to bacteriochlorins and tetradehydrocorrins

Author:

Zhang Shaofei1234,Nagarjuna Reddy Muthyala1234,Mass Olga1234,Kim Han-Je12345ORCID,Hu Gongfang1234,Lindsey Jonathan S.1234ORCID

Affiliation:

1. Department of Chemistry

2. North Carolina State University

3. Raleigh

4. USA

5. Department of Science Education

Abstract

18 gem-dimethyl stabilized hydrodipyrrins with diverse α-substituents have been prepared and examined in directed syntheses of unsymmetrically substituted hydroporphyrins.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference63 articles.

1. H. Scheer , in Chlorophylls and Bacteriochlorophylls: Biochemistry, Biophysics, Functions and Applications, ed. B. Grimm, R. J. Porra, W. Rüdiger and H. Scheer, Springer, Dordrecht, The Netherlands, 2006, pp. 1–26

2. M. Kobayashi , M.Akiyama, H.Kano and H.Kise, in Chlorophylls and Bacteriochlorophylls: Biochemistry, Biophysics, Functions and Applications, ed. B. Grimm, R. J. Porra, W. Rüdiger and H. Scheer, Springer, Dordrecht, The Netherlands, 2006, pp. 79–94

3. Description of the corrinoid species herein follows IUPAC nomenclature, Pure Appl. Chem. 1976, 48 495–502

4. Synthesis of Corroles and Octadehydrocorrins

5. The Structure and Reactivity of Octadehydrocorrins and Corroles

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