A stable gold(i)–enyne species obtained by alkyne carboauration in a complex rearrangement-Reference-Cited by-同舟云学术

A stable gold(i)–enyne species obtained by alkyne carboauration in a complex rearrangement

Published:2017 Issue:66 Volume:53 Page:9202-9205
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cámara Jéssica¹²³⁴⁵,Blanco M. Carmen¹²³⁴⁵^ORCID,Laguna Antonio¹²³⁴⁵^ORCID,Naumov Panče⁶⁷^ORCID,Gimeno M. Concepción¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

3. CSIC-Universidad de Zaragoza

4. E-50009 Zaragoza

5. Spain

6. New York University Abu Dhabi

7. United Arab Emirates

Abstract

An unprecedented tetranuclear gold derivative with unusual gold–enyne moieties is prepared by a mild and neat rearrangement of a dinuclear gold complex with a bridging bis(diphenylphosphino)alkyne and terminal alkynyl ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC03713A

Reference40 articles.

1. Gold-Catalyzed Organic Reactions

2. Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

3. Relativistic effects in homogeneous gold catalysis

4. Regioselectivity in the Au-catalyzed hydration and hydroalkoxylation of alkynes

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