Controlled di-lithiation enabled synthesis of phosphine-sulfonamide ligands and implications in ethylene oligomerization-Reference-Cited by-同舟云学术

Controlled di-lithiation enabled synthesis of phosphine-sulfonamide ligands and implications in ethylene oligomerization

Published:2021 Issue:10 Volume:50 Page:3717-3723
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mote Nilesh R.¹²³⁴⁵,Gaikwad Shahaji R.¹²³⁴⁵,Khopade Kishor V.¹²³⁴⁵,Gonnade Rajesh G.⁶³⁴⁵^ORCID,Chikkali Samir H.¹²³⁴⁵^ORCID

Affiliation:

1. Polyolefin Laboratory

2. Polymer Science and Engineering Division

3. CSIR-National Chemical Laboratory

4. Pune-411008

5. India

6. Center for Materials Characterization

Abstract

Arresting dilithiation intermediate at −84/−41 °C selectively produced L1A/L1B and L2A/L2B, respectively, from a single precursor. Pd-Complexes C1–C7 were prepared, fully characterized and their performance in ethylene oligomerization was studied.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00093D

Reference45 articles.

1. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships

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