Synthesis and characterization of new heterometallic cyanido complexes based on [Co(CN)6]3− building blocks: crystal structure of [Cu2(N-bishydeten)2Co(CN)6]·3H2O having a strong antiferromagnetic exchange-Reference-Cited by-同舟云学术

Synthesis and characterization of new heterometallic cyanido complexes based on [Co(CN)6]3− building blocks: crystal structure of [Cu2(N-bishydeten)2Co(CN)6]·3H2O having a strong antiferromagnetic exchange

Published:2014 Issue:11 Volume:38 Page:5402-5410
ISSN:1144-0546
Container-title:New J. Chem.
language:en
Short-container-title:New J. Chem.

Author:

Korkmaz Şengül Aslan¹²³⁴,Karadağ Ahmet⁵⁶⁷⁸,Yerli Yusuf⁹⁶¹⁰¹¹,Soylu Mustafa Serkan⁹⁶¹²¹³

Affiliation:

1. Bioengineering Department

2. Engineering Faculty

3. Tunceli University

4. Tunceli, Turkey

5. Department of Chemistry

6. Art and Science Faculty

7. Gaziosmanpaşa University

8. Tokat, Turkey

9. Department of Physics

10. Yıldız Technical University

11. stanbul, Turkey

12. Giresun University

13. Giresun, Turkey

Abstract

The hexacyanidocobalt(iii)-based four new coordination compounds have been synthesized and characterized by various techniques. The polymeric C2 having 148.3 Å³ lattice spacing among these complexes have shown very strong antiferromagnetic interaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/NJ/C4NJ00737A

Reference52 articles.

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2. Synthesis, crystal structure and properties of the cyano-bridged heteropolynuclear [Cu(meso)]3[Co(CN)6]29.5H2O compound

3. One Novel Racemic Cu–Co Cyano-Bridged Complex: Synthesis, Characterization, Crystal Structure, and Magnetic Properties

4. Structure and Magnetic Properties of One-Dimensional PPh4[Ni(pn)2][M(CN)6]·H2O (M = Fe, Cr, Co) Bimetallic Assemblies

5. Synthesis and characterization of cyano-bridged polynuclear [Cu(dmpn)2]3[Co(CN)6]2·12H2O and trinuclear [Cu(dmpn)2]2[Co(CN)6]·ClO4·3H2O complexes

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