The influence of the cation structure on the basicity-related polarity of ionic liquids

Author:

Weiß Nadine1ORCID,Thielemann Gabi1ORCID,Nagel Kevin1ORCID,Schmidt Caroline H.1ORCID,Seifert Andreas1ORCID,Kaßner Lysann1,Strehmel Veronika2ORCID,Corzilius Björn3ORCID,Schröder Christian4ORCID,Spange Stefan1ORCID

Affiliation:

1. Department of Polymer Chemistry, Institute of Chemistry, Chemnitz University of Technology, Straße der Nationen 62, 09111 Chemnitz, Germany

2. Department of Chemistry, Organic Chemistry and Institute for Coatings and Surface Chemistry, Hochschule Niederrhein, University of Applied Sciences, Adlerstraße 32, 47798 Krefeld, Germany

3. Institute of Chemistry, University Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany

4. Institute of Computational Biological Chemistry, University of Vienna, Währingerstr. 17, 1090 Vienna, Austria

Abstract

The solvatochromic ThTCF probe responds to anion coordination. Correlations of UV/Vis data from ThTCF with various basicity-related polarity scales (Kamlet-Taft β, Freire EHB, Laurence β1) allow an evaluation of their physical significance.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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