Structure and dynamics of aqueous 2-propanol: a THz-TDS, NMR and neutron diffraction study-Reference-Cited by-同舟云学术

Structure and dynamics of aqueous 2-propanol: a THz-TDS, NMR and neutron diffraction study

Published:2015 Issue:45 Volume:17 Page:30481-30491
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

McGregor James¹²³⁴^ORCID,Li Ruoyu¹²³⁴,Zeitler J. Axel¹²³⁴^ORCID,D'Agostino Carmine¹²³⁴,Collins James H. P.¹²³⁴,Mantle Mick D.¹²³⁴,Manyar Haresh⁵⁶⁷⁴,Holbrey John D.⁵⁶⁷⁴,Falkowska Marta⁵⁶⁷⁴,Youngs Tristan G. A.⁸⁶⁷⁴,Hardacre Christopher⁵⁶⁷⁴,Stitt E. Hugh⁹¹⁰⁴,Gladden Lynn F.¹²³⁴

Affiliation:

1. Department of Chemical Engineering and Biotechnology

2. University of Cambridge

3. Cambridge CB2 3RA

4. UK

5. School of Chemistry and Chemical Engineering

6. Queen's University Belfast

7. Belfast BT9 5AG

8. School of Mathematics and Physics

9. Johnson Matthey Catalysts

10. Cleveland TS23 1LB

Abstract

90 mol_H2O% is identified as a critical composition at which alcohol–water interactions are maximised; with 4–5 H₂O molecules present in the hydration shell per 2-propanol.

Funder

Engineering and Physical Sciences Research Council

Science and Technology Facilities Council

Research Councils UK

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01132A

Reference66 articles.

1. Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K < T < 295 K