Recycling post-consumer PLA into acrylic acid or lactide using phosphonium ionic liquids

Author:

Janssens Kwinten1ORCID,Stuyck Wouter1ORCID,Stiers Kirsten1,Wéry Jens1ORCID,Smet Mario2,De Vos Dirk E.1ORCID

Affiliation:

1. Department of Microbial and Molecular Systems (M2S), Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

2. Department of Chemistry, Polymer Chemistry and Materials, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

Abstract

Post-consumer poly(lactic acid) (PLA) is recycled to high value monomers, either acrylic acid (AA) or lactide (LAC), using a phosphonium ionic liquid as the active solvent, in the presence or absence of an acid cocatalyst.

Funder

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Reference25 articles.

1. PlasticsEurope , Plastics – The Facts 2021. An analysis of European Plastics Production, Demand and Waste Data , https://plasticseurope.org/wp-content/uploads/2021/12/Plastics-the-Facts-2021-web-final.pdf

2. PlasticsEurope , The Circular Economy for Plastics. A European Overview , https://plasticseurope.org/wp-content/uploads/2022/06/PlasticsEurope-CircularityReport-2022_2804-Light.pdf

3. Chemical recycling to monomer for an ideal, circular polymer economy

4. Recycling of poly(ethylene terephthalate) – A review focusing on chemical methods

5. Chemical Recycling of PET in the Presence of the Bio-Based Polymers, PLA, PHB and PEF: A Review

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