Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide-Reference-Cited by-同舟云学术

Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide

Published:2022 Issue:23 Volume:24 Page:4174-4179
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Volkov Sergey N.¹²^ORCID,Charkin Dmitri O.¹³,Arsentev Maxim Yu.²^ORCID,Aksenov Sergey M.¹⁴,Manelis Lev S.³,Krzhizhanovskaya Maria G.²⁵,Sinelshchikova Olga Yu.²,Ugolkov Valery L.²,Povolotskiy Alexey V.⁶,Shilovskikh Vladimir V.⁷⁸^ORCID,Antonov Andrey A.⁹,Bubnova Rimma S.²

Affiliation:

1. Laboratory of Arctic Mineralogy and Material Sciences, Kola Science Centre, Russian Academy of Sciences, Fersman str. 14, Apatity, 184209, Russia

2. Grebenshchikov Institute of Silicate Chemistry, Makarov Emb, 2, St. Petersburg, 199053, Russia

3. Department of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, Moscow, 119991, Russia

4. Geological Institute, Kola Science Centre, Russian Academy of Sciences, Fersman str. 14, Apatity 184209, Russia

5. Department of Crystallography, Institute of Earth Sciences, Saint Petersburg State University, University Emb. 7/9, St. Petersburg, 199034, Russia

6. Institute of Chemistry, Saint Petersburg State University, Ulianovskaya 5, St. Petersburg, 198504, Russia

7. Geomodel Centre, St. Petersburg State University, Uliyanovskaya str. 1, St. Petersburg, 198504, Russia

8. ITMO University, Lomonosova str., 9, St. Petersburg, 191002, Russia

9. Laboratory of Nature-Inspired Technologies and Environmental Safety of the Arctic, Kola Science Centre, Russian Academy of Sciences, Fersmana str. 14, Apatity, 184209, Russia

Abstract

A new silver iodide borate, Ag3B6O10I, is presented as a promising solid-state electrolyte with a δ ↔ γ ↔ β ↔ α cascade of the isosymmetric superionic phase transitions.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00307D

Reference48 articles.

1. Borates: A Rich Source for Optical Materials

2. Structure and Ion Exchange Properties of a New Cobalt Borate with a Tunnel Structure “Templated” by Na+