Peralkylated imidazolium carbonate ionic liquids: synthesis using dimethyl carbonate, reactivity and structure
Author:
Affiliation:
1. Department of Sustainable Chemistry and Technology
2. Ghent University
3. 9000 Ghent
4. Belgium
5. Department of Inorganic and Physical Chemistry
Abstract
Tri- and tetra-alkylimidazoles are quaternised into their corresponding ionic liquids with dimethyl carbonate.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C4NJ01301H
Reference29 articles.
1. The Chemistry of Dimethyl Carbonate
2. 1,3-Dimethylimidazolium-2-carboxylate: the unexpected synthesis of an ionic liquid precursor and carbene-CO2 adductElectronic supplementary information (ESI) available: experimental data for 1,3-dimethylimidazolium-2-carboxylate. Supplemental crystal structure data. ORTEP, hydrogen bonding and packing diagrams. See http://www.rsc.org./suppdata/cc/b2/b211519k/
3. On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide
4. Demonstration of Chemisorption of Carbon Dioxide in 1,3-Dialkylimidazolium Acetate Ionic Liquids
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