Hydrogen-bonding engineering in a 3D cyano-bridged double-perovskite ferroelastic greatly improves the phase-transition temperature

Author:

Li Meng-Zhen1,Chen Zhao-Hong1,Hu Sheng-Qian1,Zhou Jun-Si1,Ji Luan-Ying1,Chen Xiao-Gang1ORCID

Affiliation:

1. Ordered Matter Science Research Center, Nanchang University, 330031, P. R. China

Abstract

Introducing a hydroxyl group on the ethylamine cation in three-dimensional cyano-bridged double perovskites effectively enhances cation–cation and cation–framework interactions, thus increasing the phase-transition temperature by 88 K.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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