Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(ii) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand-Reference-Cited by-同舟云学术

Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(ii) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand

Published:2018 Issue:64 Volume:54 Page:8869-8872
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mitsuhashi Ryoji¹²³⁴⁵^ORCID,Pedersen Kasper S.⁶⁷⁸⁹,Ueda Takaaki¹²³⁴⁵,Suzuki Takayoshi⁶¹⁰¹¹¹²⁵,Bendix Jesper⁶¹³¹⁴⁹^ORCID,Mikuriya Masahiro¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry for Environment

2. School of Science and Technology

3. Kwansei Gakuin University

4. Hyogo 669-1337

5. Japan

6. Department of Chemistry

7. Technical University of Denmark

8. Kongens Lyngby 2800

9. Denmark

10. Faculty of Science

11. Okayama University

12. Okayama 700-8530

13. University of Copenhagen

14. Copenhagen

Abstract

A new cobalt(ii) field-induced single-molecule magnet with an ideal trigonal antiprismatic geometry was prepared taking advantage of structure-directing intermolecular hydrogen-bonds.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04756A

Reference22 articles.

1. Two Polymorphic Forms of a Six-Coordinate Mononuclear Cobalt(II) Complex with Easy-Plane Anisotropy: Structural Features, Theoretical Calculations, and Field-Induced Slow Relaxation of the Magnetization

2. A Click‐Functionalized Single‐Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds

3. Tuning Transverse Anisotropy in CoIII–CoII–CoIII Mixed-Valence Complex toward Slow Magnetic Relaxation

4. Field-Induced Slow Magnetic Relaxation in a Six-Coordinate Mononuclear Cobalt(II) Complex with a Positive Anisotropy

5. Slow Magnetic Relaxation in a CoII-YIIISingle-Ion Magnet with Positive Axial Zero-Field Splitting

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