Physical adsorption of OH<sup>−</sup> causes anomalous charging at oxide–water interfaces-Reference-Cited by-同舟云学术

Physical adsorption of OH⁻ causes anomalous charging at oxide–water interfaces

Published:2024 Issue:68 Volume:60 Page:9113-9116
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Yingchun¹^ORCID,Zhuang Yong-Bin²^ORCID,Liu Xiandong¹^ORCID,Cheng Jun²³^ORCID,Lützenkirchen Johannes⁴^ORCID,Lu Xiancai¹

Affiliation:

1. State Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, Nanjing, Jiangsu 210023, P. R. China

2. State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, P. R. China

3. Tan Kah Kee Innovation Laboratory, Xiamen University, Xiamen, Fujian 361005, P. R. China

4. Institute of Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

Abstract

The special interfacial structure of inert oxide surfaces effectively traps OH− through physical adsorption, causing obvious zeta potentials.

Funder

National Natural Science Foundation of China

Nanjing University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01833H

Reference30 articles.

1. J.Lyklema , Fundamentals of Interface and Colloid Science: Solid-Liquid Interfaces , Academic Press , London , 1995

2. Zeta potential of artificial and natural calcite in aqueous solution

3. The relationship between inner surface potential and electrokinetic potential from an experimental and theoretical point of view

4. Structures and Charging of α-Alumina (0001)/Water Interfaces Studied by Sum-Frequency Vibrational Spectroscopy

5. An attempt to explain bimodal behaviour of the sapphire c-plane electrolyte interface