Can the absolute configuration of cyclic peptides be determined with vibrational circular dichroism?-Reference-Cited by-同舟云学术

Can the absolute configuration of cyclic peptides be determined with vibrational circular dichroism?

Published:2023 Issue:20 Volume:25 Page:14520-14529
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Eikås Karolina Di Remigio¹^ORCID,Krupová Monika¹^ORCID,Kristoffersen Tone²^ORCID,Beerepoot Maarten T. P.²^ORCID,Ruud Kenneth¹³^ORCID

Affiliation:

1. Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, UiT The Arctic University of Norway, 9037 Tromsø, Norway

2. Department of Chemistry, UiT The Arctic University of Norway, 9037 Tromsø, Norway

3. Norwegian Defence Research Establishment, P.O. Box 25, 2027 Kjeller, Norway

Abstract

The absolute configuration of cyclic peptides with two chiral centers can be unambiguously assigned with VCD. This is however not possible with three or four chiral centers. Hence, other techniques are needed to supplement VCD.

Funder

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP04942B

Reference49 articles.

1. A gold mine for drug discovery: Strategies to develop cyclic peptides into therapies

2. Natural Cyclic Peptides as an Attractive Modality for Therapeutics: A Mini Review

3. Cyclic peptide therapeutics: past, present and future

4. Chiral Toxicology: It's the Same Thing…Only Different

5. Structure elucidation of small organic molecules by contemporary computational chemistry methods

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