Chiral spin-crossover complexes based on an enantiopure Schiff base ligand with three chiral carbon centers

Author:

Regueiro Alejandro1,García-López Víctor1ORCID,Forment-Aliaga Alicia1ORCID,Clemente-León Miguel1ORCID

Affiliation:

1. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980 Paterna, Spain

Abstract

Four enantiopure spin-crossover complexes have been prepared in which the unexpected incorporation of acetone leads to an additional chiral center.

Funder

Ministerio de Ciencia, Innovación y Universidades

Generalitat Valenciana

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Reference31 articles.

1. Spin Crossover in Transition Metal Compounds, Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer Verlag , Berlin-Heidelberg-New York , 2004 , vol. 233–235

2. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013

3. Emerging trends in spin crossover (SCO) based functional materials and devices

4. 90-degree optical switching of output second-harmonic light in chiral photomagnet

5. Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

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