Understanding the initial events of the oxidative damage and protection mechanisms of the AA9 lytic polysaccharide monooxygenase family-Reference-Cited by-同舟云学术

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Understanding the initial events of the oxidative damage and protection mechanisms of the AA9 lytic polysaccharide monooxygenase family

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hagemann Marlisa M.¹^ORCID,Wieduwilt Erna K.¹^ORCID,Hedegård Erik D.¹^ORCID

Affiliation:

1. Department of Physics, Chemistry, and Pharmacy, University of Southern Denmark, Campusvej 55, 5230, Odense, Denmark

Abstract

We employed a QM/MM model for two different LPMOs and show that the direct oxidation of a tyrosine is crucial for protection against oxidative damage, while the formation of a tyrosyl via a histidyl is generally not feasible.

Funder

Vetenskapsrådet

Danmarks Frie Forskningsfond

Villum Fonden

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05933B

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4. A review on the pretreatment of lignocellulose for high-value chemicals

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