Initial metal–metal bond breakage detected by fs X-ray scattering in the photolysis of Ru3(CO)12 in cyclohexane at 400 nm-Reference-Cited by-同舟云学术

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Initial metal–metal bond breakage detected by fs X-ray scattering in the photolysis of Ru3(CO)12 in cyclohexane at 400 nm

Published:2019 Issue:2 Volume:18 Page:319-327
ISSN:1474-905X
Container-title:Photochemical & Photobiological Sciences
language:en
Short-container-title:Photochem. Photobiol. Sci.

Author:

Kong Q. Y.¹²³^ORCID,Laursen M. G.⁴⁵⁶⁷,Haldrup K.⁴⁵⁶⁷,Kjær K. S.⁴⁵⁶⁷^ORCID,Khakhulin D.⁸⁹¹⁰,Biasin E.⁴⁵⁶⁷¹¹,van Driel T. B.¹²¹³¹⁴¹⁵,Wulff M.¹⁶¹⁷³,Kabanova V.¹⁶¹⁷³,Vuilleumier R.¹⁸¹⁹²⁰²¹²²,Bratos S.²³²⁰²⁴²⁵²⁶,Nielsen M. M.⁴⁵⁶⁷^ORCID,Gaffney K. J.¹¹¹³¹⁴¹⁵,Weng T. C.²⁷²⁸²⁹,Koch M. H. J.³⁰³¹¹⁰

Affiliation:

1. Synchrotron Soleil

2. F-91192 Gif-sur-Yvette

3. France

4. Department of Physics

5. Technical University of Denmark

6. DK-2800 Kongens Lyngby

7. Denmark

8. European XFEL GmbH

9. D-22869 Schenefeld

10. Germany

11. PULSE Institute

12. LCLS

13. SLAC National Accelerator Laboratory

14. Menlo Park

15. USA

16. European Synchrotron Radiation Facility

17. F-38043 Grenoble Cedex

18. Ecole Normale Supérieure

19. PSL Research University

20. UPMC Univ Paris 06

21. CNRS

22. Département de Chimie

23. Sorbonne Universités

24. UMR 7600

25. LPTMC

26. F-75005 Paris

27. Center for High Pressure Science & Technology Advanced Research

28. Pudong

29. P.R. China

30. European Molecular Biology Laboratory

31. D-22603 Hamburg

Abstract

fs X-ray solution scattering reveals selective metal–metal bond cleavage and a new intermediate in the photolysis of Ru₃(CO)₁₂ at 400 nm.

Funder

Basic Energy Sciences

Det Frie Forskningsråd

Carlsbergfondet

Horizon 2020 Framework Programme

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/PP/C8PP00420J

Reference31 articles.

1. Tracking excited-state charge and spin dynamics in iron coordination complexes

2. Direct observation of bond formation in solution with femtosecond X-ray scattering

3. Atomistic characterization of the active-site solvation dynamics of a model photocatalyst

4. Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses

5. Femtosecond X-Ray Scattering Study of Ultrafast Photoinduced Structural Dynamics in Solvated[Co(terpy)2]2+

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2. Cerium Photocatalyst in Action: Structural Dynamics in the Presence of Substrate Visualized via Time-Resolved X-ray Liquidography;Journal of the American Chemical Society;2023-10-19

3. Evolution of Graphene Supported Ru _N (N=1–4) Clusters in CO Atmosphere: A First‐Principles Investigation;European Journal of Inorganic Chemistry;2023-01-19

4. IR spectra and structures of saturated ruthenium cluster carbonyl cations Ru_n(CO)_m⁺ (n = 1–6);Dalton Transactions;2023

5. X-ray free-electron lasers and their applications in ultrafast structural dynamics research;SCIENTIA SINICA Physica, Mechanica & Astronomica;2022-06-10

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