Copper and manganese co-mediated cascade aza-Michael addition/cyclization and azidation of 1,3-enynes: regioselective synthesis of fully substituted azido pyrroles-Reference-Cited by-同舟云学术

Copper and manganese co-mediated cascade aza-Michael addition/cyclization and azidation of 1,3-enynes: regioselective synthesis of fully substituted azido pyrroles

Published:2020 Issue:43 Volume:18 Page:8908-8915
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ge Junying¹²³⁴⁵,Ding Qiuping¹²³⁴⁵^ORCID,Yang Man¹²³⁴⁵,He Tian¹²³⁴⁵,Peng Yiyuan¹²³⁴⁵

Affiliation:

1. Key Laboratory of Functional Small Organic Molecules

2. Ministry of Education

3. Jiangxi Normal University

4. Nanchang 330022

5. China

Abstract

A Cu and Mn co-mediated aerobic oxidative cyclization and azidation reaction of 1,3-enynes with amines and trimethylsilyl azide has been developed to synthesize fully substituted azido pyrroles.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01927E

Reference55 articles.

1. New amination strategies based on nitrogen-centered radical chemistry

2. Recent advances in the synthesis of aromatic nitro compounds