A thermodynamical and structural study on the complexation of trivalent lanthanides with a polycarboxylate based concrete superplasticizer-Reference-Cited by-同舟云学术

A thermodynamical and structural study on the complexation of trivalent lanthanides with a polycarboxylate based concrete superplasticizer

Published:2017 Issue:12 Volume:46 Page:4093-4100
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fröhlich Daniel R.¹²³⁴^ORCID,Maiwald Martin M.¹²³⁴⁵,Taube Franziska⁶⁷⁸⁹¹⁰,Plank Johann¹¹¹²¹³⁴,Panak Petra J.¹²³⁴⁵

Affiliation:

1. Ruprecht-Karls-Universität Heidelberg

2. Physikalisch-Chemisches Institut

3. 69120 Heidelberg

4. Germany

5. Karlsruher Institut für Technologie

6. Technische Universität Dresden

7. Fakultät Mathematik und Naturwissenschaften

8. Fachrichtung Chemie und Lebensmittelchemie

9. Professur für Radiochemie/Radioökologie

10. 01062 Dresden

11. Technische Universität München

12. Lehrstuhl für Bauchemie

13. 85747 Garching

Abstract

Thermodynamic data for the complexation of Eu(iii) with a polycarboxylate based concrete superplasticizer are determined by TRLFS. These results are complemented by structural data of the respective Gd(iii) and Tb(iii) complexes which are obtained using EXAFS spectroscopy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00200A

Reference23 articles.

1. Multi-method approach to study influence of superplasticizers on cement suspensions

2. Influence of superplasticizers on the long-term properties of cement pastes and possible impact on radionuclide uptake in a cement-based repository for radioactive waste

3. Thorium and americium solubilities in cement pore water containing superplasticiser compared with thermodynamic calculations

4. Complexation of Metal Ions with Humic Acid: Metal Ion Charge Neutralization Model

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