[2+2] Cycloaddition or β-hydrogen elimination?—a DFT study of the reactions of propylene catalyzed by (PDI)Fe-metallacycle-Reference-Cited by-同舟云学术

[2+2] Cycloaddition or β-hydrogen elimination?—a DFT study of the reactions of propylene catalyzed by (PDI)Fe-metallacycle

Published:2022 Issue:9 Volume:46 Page:4052-4056
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Jiao Mingyang¹²³^ORCID,Wang Zichen¹,Zhang Beibei¹,Chen Bo-Zhen¹^ORCID

Affiliation:

1. School of Chemical Sciences, University of Chinese Academy of Sciences, No. 19A, YuQuan Road, Beijing 100049, P. R. China

2. CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, P. R. China

3. Shandong Energy Institute, Qingdao 266101, Shandong, P. R. China

Abstract

The origin of the chemoselectivity of [2+2] cycloaddition reactions catalyzed by different (PDI)Fe-metallacycles is due to the different groups (N2 or CH3) coordinated with the Fe metal.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ05646H

Reference26 articles.

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4. Total Synthesis and Structural Revision of the Piperarborenines via Sequential Cyclobutane C–H Arylation

5. Photochemical Reactions as Key Steps in Natural Product Synthesis

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