A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes
Author:
Affiliation:
1. Henan Key Laboratory of Polyoxometalate Chemistry
2. Institute of Molecular and Crystal Engineering
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng
Abstract
We synthesized a new phosphotungstate-supported rhenium carbonyl derivative, [N(CH3)4]6H4[P2W17O62{Re(CO)3}2]·25H2O, existing the first {Re2} fragment. Moreover, it also exhibits high efficiency for the selective oxidation of thiophenes.
Funder
National Natural Science Foundation of China
National Basic Research Program of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE01124B
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