Water-controlled selective preparation of α-mono or α,α′-dihalo ketones via catalytic cascade reaction of unactivated alkynes with 1,3-dihalo-5,5-dimethylhydantoin-Reference-Cited by-同舟云学术

Water-controlled selective preparation of α-mono or α,α′-dihalo ketones via catalytic cascade reaction of unactivated alkynes with 1,3-dihalo-5,5-dimethylhydantoin

Published:2017 Issue:8 Volume:19 Page:1983-1989
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wu Chao¹²³⁴⁵,Xin Xiu¹²³⁴⁵,Fu Zhi-Min¹²³⁴⁵,Xie Long-Yong¹²³⁴⁵,Liu Kai-Jian¹²³⁴⁵,Wang Zheng¹²³⁴⁵,Li Wenyi¹²³⁴⁵,Yuan Zhi-Hui¹²³⁴⁵,He Wei-Min¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Comprehensive Utilization of Advantage Plants Resources in Hunan South

2. College of Chemistry and Bioengineering

3. Hunan University of Science and Engineering

4. Yongzhou 425100

5. China

Abstract

An efficient protocol for the selective synthesis of α-mono or α,α′-dihalo ketones via a water-controlled chemodivergent and regiospecific cascade reaction has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC00283A

Reference75 articles.

1. Simple and efficient methods for selective preparation of α-mono or α,α-dichloro ketones and β-ketoesters by using DCDMH

2. Copper(II)-Catalyzed Silylation of Activated Alkynes in Water: Diastereodivergent Access toE- orZ-β-Silyl-α,β-Unsaturated Carbonyl and Carboxyl Compounds

3. Pd(ii)-catalyzed remote regiodivergent ortho- and meta-C–H functionalizations of phenylethylamines